Platinum-group elements distribution and spinel composition in podiform chromitites and associated rocks from the upper mantle section of the Neoproterozoic Bou Azzer ophiolite, Anti-Atlas, Morocco     

Ahmed H. Ahmed  Shoji Arai  Yaser M. Abdel-Aziz  Moha Ikenne  Abdellatif Rahimi 《Journal of African Earth Sciences》2009,55(1-2):92

The distribution of platinum-group elements (PGEs), together with spinel composition, of podiform chromitites and serpentinized peridotites were examined to elucidate the nature of the upper mantle of the Neoproterozoic Bou Azzer ophiolite, Anti-Atlas, Morocco. The mantle section is dominated by harzburgite with less abundant dunite. Chromitite pods are also found as small lenses not exceeding a few meters in size. Almost all primary silicates have been altered, and chromian spinel is the only primary mineral that survived alteration. Chromian spinel of chromitites is less affected by hydrothermal alteration than that of mantle peridotites. All chromitite samples of the Bou Azzer ophiolite display a steep negative slope of PGE spidergrams, being enriched in Os, Ir and Ru, and extremely depleted in Pt and Pd. Harzburgites and dunites usually have intermediate to low PGE contents showing more or less unfractionated PGE patterns with conspicuous positive anomalies of Ru and Rh. Two types of magnetite veins in serpentinized peridotite, type I (fibrous) and type II (octahedral), have relatively low PGE contents, displaying a generally positive slope from Os to Pd in the former type, and positive slope from Os to Rh then negative from Rh to Pd in the latter type. These magnetite patterns demonstrate their early and late hydrothermal origin, respectively. Chromian spinel composition of chromitites, dunites and harzburgites reflects their highly depleted nature with little variations; the Cr# is, on average, 0.71, 0.68 and 0.71, respectively. The TiO₂ content is extremely low in chromian spinels, <0.10, of all rock types. The strong PGE fractionation of podiform chromitites and the high-Cr, low-Ti character of spinel of all rock types imply that the chromitites of the Bou Azzer ophiolite were formed either from a high-degree partial melting of primitive mantle, or from melting of already depleted mantle peridotites. This kind of melting is most easily accomplished in the supra-subduction zone environment, indicating a genetic link with supra-subduction zone magma, such as high-Mg andesite or arc tholeiite. This is a general feature in the Neoproterozoic upper mantle.  相似文献   

Recent macroids on the Kikai‐jima shelf,Central Ryukyu Islands,Japan     

DAVIDE BASSI  YASUFUMI IRYU  MARC HUMBLET  HIROKI MATSUDA  HIDEAKI MACHIYAMA  KEIICHI SASAKI  SHINYA MATSUDA  KOHSAKU ARAI  TAKAHIKO INOUE 《Sedimentology》2012,59(7):2024-2041

Sandy and gravelly carbonate sediments found off Kikai‐jima, southern Japan, a coral reef‐related island shelf, represent the northernmost sub‐tropical, carbonate deposits in the Central Ryukyu Islands (Ryukyus). On the Kikai‐jima shelf, at water depths of 61 to 105 m, these sediments are characterized by macroid pavements. Since the abundance of very small and of exceptionally large macroids may indicate specific hydrodynamic controls regarding constraints on growth and taphonomy, the detailed analysis of recent and fossil macroid pavements is meaningful ecologically and environmentally. Macroids, ranging in size from ca 25 to 130 mm in diameter, are spheroidal and sub‐spheroidal in shape and consist mainly of the encrusting foraminifer Acervulina inhaerens and subordinate thin encrusting and lumpy coralline algae. Accessory components include bryozoans, serpulids and, to a lesser extent, encrusting arborescent foraminifera (Homotrema and Miniacina). Low sedimentation rates and occasional movement due to current action are indicated by sizes, shapes and growth‐forms of the studied macroids, the Entobia–Gastrochaenolites–Trypanites–Maeandropolydora ichnocoenosis and the ‘Bioerosion Index’ for coated grains (introduced herein). The deep‐water tidally induced current energy was sufficient to maintain multi‐directional growth (spheroidal shapes) of the larger macroids and to initiate macroid growth using the diverse biogenic remnants as nuclei. The asymmetrical inner arrangement suggests possible periods of stability for the macroids. The residence time of the coated grain in its original environment determines the size and morphology of the macroid and the selection of coating organisms. The composition of the coating community is mainly a consequence of component growth rates in relation to turnover time and residence time. Long‐term studies are needed to assess the spatial and temporal resolution of present‐day encrusting communities across biogeographic provinces and shelf to slope regions.  相似文献   

Hydrous peridotites with Ti-rich chromian spinel as a low-temperature forearc mantle facies: evidence from the Happo-O’ne metaperidotites (Japan)   总被引：1，自引：0，他引：1  

Mohamed Zaki Khedr  Shoji Arai 《Contributions to Mineralogy and Petrology》2010,159(2):137-157

The Happo-O’ne peridotite complex is situated in the northeastern part of the Hida Marginal Tectonic Zone, central Japan, characterized by the high-P/T Renge metamorphism, and is considered as a serpentinite mélange of Paleozoic age. Peridotitic rocks, being massive or foliated, have been subjected to hydration and metamorphism. Their protoliths are mostly lherzolites to harzburgites with subordinate dunites. We found a characteristic mineral assemblage, olivine + orthopyroxene + tremolite + chlorite + chromian spinel, being stable at low-T, from 650 to 750°C, and high-P, from 16 to 20 kbar, tremolite–chlorite peridotites of the tremolite zone. Olivines are Fo₈₈–Fo_91, and orthopyroxenes (Mg# = 0.91) show low and homogenous distributions of Al₂O₃ (up to 0.25 wt%), Cr₂O₃ (up to 0.25 wt%), CaO (up to 0.36 wt%) and TiO₂ (up to 0.06 wt%) due to the low equilibration temperature. Chromian spinels, which are euhedral and enclosed mainly in the orthopyroxenes, have high TiO_2, 3.1 wt% (up to 5.7 wt%) on average, and high Cr# [=Cr/(Cr + Al) atomic ratio], 0.95 on average but low Fe³⁺ [=Fe³⁺/(Cr + Al + Fe³⁺) atomic ratio, <0.3]. The bulk-rock chemistry shows that the Happo-O’ne metaperidotites with this peculiar spinel are low in TiO₂ (0.01–0.02 wt%), indicating no addition of TiO₂ from the outside source during the metamorphism; the high TiO₂ of the peculiar spinel has been accomplished by Ti release from Ti-bearing high-T pyroxenes during the formation of low-T, low-Ti silicates (<0.1 wt% TiO₂) during cooling. Some dunites are intact from hydration: their olivine is Fo₉₂ and spinel shows high Cr#, 0.72. The Happo-O’ne metaperidotites (tremolite–chlorite peridotites), being in the corner of the mantle wedge, are representative of a hydrous low-T, high-P mantle peridotite facies transitional from a higher T anhydrous peridotite facies (spinel peridotites) formed by in situ retrograde metamorphism influenced by fluids from the subducting slab. They have suffered from low-T (<600°C) retrogressive metamorphism to form antigorite and diopside during exhumation of the Renge metamorphic belt.  相似文献   

Raman spectroscopic and calorimetric observations on natural gas hydrates with cubic structures I and II obtained from Lake Baikal     

Akihiro Hachikubo  Oleg Khlystov  Masato Kida  Hirotoshi Sakagami  Hirotsugu Minami  Satoshi Yamashita  Nobuo Takahashi  Hitoshi Shoji  Gennadiy Kalmychkov  Jeffrey Poort 《Geo-Marine Letters》2012,32(5-6):419-426

This study reports measurements of the Raman spectra of Lake Baikal gas hydrates and estimations of the hydration number of methane-rich samples. The hydration number of gas hydrates retrieved from the southern Baikal Basin (crystallographic structure I) was approx. 6.1. Consistent with previous results, the Raman spectra of gas hydrates retrieved from the Kukuy K-2 mud volcano in the central Baikal Basin indicated the existence of crystallographic structures I and II. Measurements of the dissociation heat of Lake Baikal gas hydrates by calorimetry (from the decomposition of gas hydrates to gas and water), employing the hydration number, revealed values of 53.7–55.5?kJ?mol^–1 for the southern basin samples (structure I), and of 54.3–55.5?kJ?mol^–1 for the structure I hydrates and 62.8–64.2?kJ?mol^–1 for the structure II hydrates from the Kukuy K-2 mud volcano.  相似文献   

Thermal anomalies associated with shallow gas hydrates in the K-2 mud volcano, Lake Baikal     

Jeffrey Poort  Oleg M. Khlystov  Lieven Naudts  Albert D. Duchkov  Hitoshi Shoji  Shin’ya Nishio  Marc De Batist  Akihiro Hachikubo  Masato Kida  Hirotsugu Minami  Andrey Y. Manakov  Marina V. Kulikova  Alexey A. Krylov 《Geo-Marine Letters》2012,32(5-6):407-417

Thermal measurements and hydrate mapping in the vicinity of the K-2 mud volcano in Lake Baikal have revealed a particular type of association of thermal anomalies (29–121?mW?m^–2) near hydrate-forming layers. Detailed coring within K-2 showed that hydrates are restricted to two distinct zones at sub-bottom depths exceeding 70–300?cm. Temperature data from stations with hydrate recovery and degassing features all display low thermal gradients. Otherwise, the thermal gradients within the mud volcano are generally increased. These findings imply a more complicated thermal regime than often assumed for mud volcanoes, with important roles for both fluids and hydrates. The coexistence of neighbouring low and high thermal anomalies is interpreted to result from discharging and recharging fluid activity, rather than hydrate thermodynamics. It is suggested that hydrates play a key role in controlling the fluid circulation pattern at an early stage. At a later stage, the inflow of undersaturated lake water would favour the dissolution of structure I hydrates and the formation of structure II hydrates, the latter having been observed on top of structure I hydrates in the K-2 mud volcano.  相似文献   

Petrology of the Yugu peridotites in the Gyeonggi Massif,South Korea: Implications for its origin and hydration process     

Shoji Arai  Akihiro Tamura  Satoko Ishimaru  Kazuyuki Kadoshima  Yong‐Il Lee  Ken‐ichiro Hisada 《Island Arc》2008,17(4):485-501

Peridotites exposed in the Yugu area in the Gyeonggi Massif, South Korea, near the boundary with the Okcheon Belt, exhibit mylonitic to strongly porphyroclastic textures, and are mostly spinel lherzolites. Subordinate dunites, harzburgites, and websterites are associated with the lherzolites. Amphiboles, often zoned from hornblende in the core to tremolite in the rim, are found only as neoblasts. Porphyroclasts have recorded equilibrium temperatures of about 1000°C, whereas neoblasts denote lower temperatures, about 800°C. Olivines are Fo_90–91 in lherzolites and Fo₉₁ in a dunite and a harzburgite. The Cr# (= Cr/(Cr + Al) atomic ratio) of spinels varies together with the Fo of olivines, being from 0.1 to 0.3 in lherzolites and around 0.5 in the dunite and harzburgite. The Na₂O content of clinopyroxene porphyroclasts is relatively low, around 0.3 to 0.5 wt% in the most fertile lherzolite. The Yugu peridotites are similar in porphyroclast mineral chemistry not to continental spinel peridotites but to sub‐arc or abyssal peridotites. Textural and mineralogical characteristics indicate the successive cooling with hydration from the upper mantle to crustal conditions for the Yugu peridotites. Almost all clinopyroxenes and amphiboles show the same U‐shaped rare earth element (REE) patterns although the level is up to ten times higher for the latter. The hydration was associated with enrichment in light REE, resulting from either a slab‐derived fluid or a fluid circulating in the crust. The mantle‐wedge or abyssal peridotites were emplaced into the continental crust as the Yugu peridotite body during collision of continents to form a high‐pressure metamorphic belt in the Gyeonggi Massif. The peridotites from the Gyeonggi Massif exhibit lower‐pressure equilibration than peridotites, with or without garnets, from the Dabie–Sulu Collision Belt, China, which is possibly a westward extension of the Gyeonggi Massif.  相似文献   

Early Cretaceous paleogeography of Korea and Southwest Japan inferred from occurrence of detrital chromian spinels     

Ken‐ichiro Hisada  Shizuka Takashima  Shoji Arai  Yong Il Lee 《Island Arc》2008,17(4):471-484

The Sindong Group was deposited in the north–south trending half‐graben Nakdong Trough, southern Korean peninsula. The occurrence of detrital chromian spinels from the Jinju Formation of the Sindong Group in the Gyeongsang Basin means that the mafic to ultramafic rocks were exposed in its provenance. The chromian spinels from the Jinju Formation are characterized by extremely low TiO₂ and Fe³⁺. Moreover, their range of Cr# is from 0.45 to 0.80 and makes a single trend with Mg#. The chemistry of chromian spinels implies that the source rocks for chromian spinels were peridotites or serpentinites, which originated in the mantle wedge. To more narrowly constrain their source rocks, the Ulsan and Andong serpentinites exposed in the Gyeongsang Basin were examined petrographically. Chromian spinels in the Andong serpentinite differ from those of the Jinju Formation and those in the Ulsan serpentinite partly resemble them. Furthermore, the Jinju chromian spinel suite is similar to the detrital chromian spinels from the Mesozoic sediments in the Circum‐Hida Tectonic zone, which includes the Nagato Tectonic zone in Southwest Japan and the Joetsu Belt in Northeast Japan. This suggests that the basement rocks, which were located along the main fault bounding the eastern edge of the Nakdong Trough, had exposures of peridotite or serpentinite. It is possible that the Nakdong Trough was directly adjacent to the Circum‐Hida Tectonic zone before the opening of the Sea of Japan (East Sea).  相似文献   

Petrogenesis of ultramafic rocks and olivine-rich troctolites from the East Taiwan Ophiolite in the Lichi mélange     

Morishita  Tomoaki  Ghosh  Biswajit  Soda  Yusuke  Mizukami  Tomoyuki  Tani  Ken-ichiro  Ishizuka  Osamu  Tamura  Akihiro  Komaru  Chihiro  Aari  Shoji  Yang  Hsiao-Chin  Chen  Wen-Shan 《Mineralogy and Petrology》2018,112(4):521-534

Mineralogy and Petrology - We examine ultramafic and olivine-rich troctolite blocks of the East Taiwan Ophiolite (ETO) in the Lichi Mélange. Although ultramafic rocks are extensively...  相似文献   

Platinum–Group Minerals in Podiform Chromitite from the Kamuikotan Zone, Hokkaido, Northern Japan     

Shoji ARAI  Hazel M. PRICHARD  Ichiro MATSUMOTO  Peter C. FISHER 《Resource Geology》1999,49(1):39-47

Abstract: Ru–Os–Ir alloys have been found in two podiform chromitites located at the Chiroro and Bankei mines in the Sarugawa peridotite complex in the Kamuikotan zone, Hokkaido, Japan. This is the first report on the occurrence of PGM (= platinum-group minerals) from chromitites in Japan. The Ru–Os–Ir alloys most typically form polyhedra associated with other minerals (Ni–Fe alloys and heazlewoodite) in chromian spinel. The PGM are possibly pseudomorphs after some primary PGM such as laurite and are chemically highly inhomogeneous, indicating a low-temperature alteration origin. This is consistent with intense alteration (formation of serpentine, uvarovite and kämmererite) imposed on the Kamuikotan chromitites. High-temperature primary PGE (platinum–group elements)–bearing sulfides were possibly recrystallized at low temperatures into a new assemblage of PGM, Ni-Fe alloys and sulfides. Placer PGM around the peridotite complexes are chemically different from the PGM in dunite and chromitite possibly due to the, as yet, incomplete search for the rock-hosted PGM. The PGE content in chromitites is distinctly higher in those in the Kamuikotan zone than in those in the Sangun zone of Southwest Japan, consistent with the more refractory nature (Cr# of spinel, up to 0.8) of the former than the latter (Cr# of spinel, 0.5).  相似文献   

Ore value-tonnage diagrams for resource assessment   总被引：4，自引：0，他引：4  

Tetsuya Shoji  Hiroaki Kaneda 《Natural Resources Research》1998,7(1):25-36

An ore value-tonnage diagram has been proposed for assessing mineral resources. Diagrams of W+Mo, and Pb+Zn deposits show a good linearity between ore value and logarithms of cumulative ore tonnage. Diagrams of the massive sulfide, orthomagmatic, placer, porphyry, replacement, and stratabound types are also linear. It is assumed, therefore, that deposits of each of these commodities and these types belong to a single population. In contrast, the ore value-tonnage relations of all the deposits analyzed here is approximated by the combination of two exponential functions. The same feature is seen for deposits of the Cu+W+Mo, Cu+Pb+Zn, and Au+Ag commodities, and of the vein and unconformity-related types. This suggests that deposits belonging to each of such categories are divided into the high and low value groups. We can expect, accordingly, to find high value deposits of such categories.  相似文献